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Reconsider Prob. 4-15. Using the appropriate software, plot the process described in the problem on a P − v P-v P − v diagram, and investigate the effect of the polytropic exponent n n n on the boundary work.
Sep 19, 2017 · The Key Rearrangement Step In The Hofmann and Curtius. Now we get down to business. The key step in the Hofmann and Curtius rearrangments is migration of a carbon atom to displace a leaving group on an adjacent nitrogen. This requires two curved arrows to draw, which are shown in the structure on the far left (below).
1) find the chirality center 2) assign priority orders by atomic highest--> lowest atomic # 3) If a decision cannot be reached by ranking the first atoms in the substituent, look at the second, third, or fourth atoms until the difference is found 4) Multiple-bonded atoms are equivalent to the same number of single-bonded atoms 5) flip if the least group is not away then obtain rotation r ...
Study with Quizlet and memorize flashcards containing terms like Which reactions results in inversion of configuration?, _____ reactions feature a nucleophile in the rate-determining step, Carbocation rearrangements are possible in _____ reactions and more.
The atom or group of atoms that is responsible for most of the chemical reactions of a molecule. Homologous series. A family of compounds with the same general formula and similar chemical properties. In a series, each member differs by the addition of a CH2 group and there is a gradual change in physical properties. Hydration.
