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Jan 19, 2021 · We demonstrate that the CH 4 –CO 2 guest composition impacts the guest–host interactions in hydrates during static temperature measurements at 10 K, implying that these interactions are ...
- Bernadette R. Cladek, S. Michelle Everett, Marshall T. McDonnell, Matthew G. Tucker, David J. Keffer...
- 2021
SI hydrate has a cubic Pm3n (223) crystal structure, composed of 46 hydrogen-bonded H2O molecules, which form the host lattice. This structure is made up of eight cages: two small dodecahedral and...
- Bernadette R. Cladek, S. Michelle Everett, Marshall T. McDonnell, Matthew G. Tucker, David J. Keffer...
- 2021
Oct 28, 2020 · A relatively small number of guest molecules with a shorter induction time for pure guest hydrate nucleation can promote the formation of initial nuclei of a mixed hydrate. Detailed cage analysis shows that small guests such as CH 4 can induce the formation of more standard cages for mixture systems with either C 2 H 6 or C 3 H 8 systems ...
- Zhengcai Zhang, Guang-Jun Guo, Nengyou Wu, Peter G. Kusalik
- 2020
Aug 12, 2021 · The study thus gave a novel example of a host–guest mixture that is able to carry out composition-driven structural modulation and guest-induced nanotemplates. The finding broadens the horizon of host–guest chemistry and may inspire more nanoinnovation.
- Jou Tsen Ou, Tsung Kai Yang, Heng Yi Lin, Hong Yu Hsu, Tzu Jung Chen, Yi Sheng Ou, Jia Chen, Cheng Y...
- 2021
Radial distribution functions and three-dimensional density distributions provide insight into the changes in guest orientation and interactions with the host framework as a function of guest composition.
- Bernadette R. Cladek, S. Michelle Everett, Marshall T. McDonnell, Matthew G. Tucker, David J. Keffer...
- 2018
Aug 28, 2015 · This article has highlighted the state-of-the-art potential energy applications of crystalline guest-host compounds, the inorganic and water (hydrates) clathrates. The guest-host interactions of these compounds play a significant role in the structure, stability, and properties of these materials.
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Oct 5, 2016 · Specifically, when studying host–guest interactions, by resolving characteristic Δω one can determine (i) guest entrapment, (ii) location/composition of the guest within the host, (iii) binding constants, and (iv) molecular recognition.
