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- Season 4 overviewSep 13, 2010-May 16, 201122 episodesSeason 4 episodes1. Belles de Jour Sep 13, 2010
- Chuck arrives in Paris with a beautiful new woman; Dan's drama with Georgina continues.
- 2. Double Identity Sep 20, 2010
- Lily asks Serena to help her find Chuck; Juliet offers to help Nate win Serena back.
- 3. The Undergraduates Sep 27, 2010
- Blair is in for a few big surprises on her first day at Columbia; Serena grows suspicious of Juliet.
- 4. Touch of Eva Oct 4, 2010
- Nate decides to confront Juliet when he thinks she is keeping a secret from him.
- 5. Goodbye, Columbia Oct 11, 2010
- A damaging rumor about Serena is started; a mysterious student thwarts Blair's plans.
- 6. Easy J Oct 25, 2010
- Jenny is tempted by a chance to meet Tim Gunn; Serena discovers something about her new boyfriend.
- 7. War at the Roses Nov 1, 2010
- A surprise guest catches Blair off-guard at her birthday party.
- 8. Juliet Doesn't Live Here Anymore Nov 8, 2010
- Blair and Chuck decide to end their vindictive games; one of Juliet's secrets is discovered.
- 9. The Witches of Bushwick Nov 15, 2010
- Chuck hosts a masquerade party at the Empire Hotel; Nate and Dan are confused by Serena's behavior.
- 10. Gaslit Nov 29, 2010
- A family member is hospitalized; Nate tries to help his parents reconcile.
- 11. The Townie Dec 6, 2010
- Dan and Blair search for Juliet; Chuck suspects Lily isn't telling the whole truth.
- 12. The Kids Are Not All Right Jan 24, 2011
- One of Bart Bass' former associates and his daughter, Raina, return to Manhattan.
- 13. Damien Darko Jan 31, 2011
- Blair's excitement at landing an internship dampens when she discovers Dan did too.
- 14. Panic Roommate Feb 7, 2011
- Blair asks Nate to help her gain favor with her high-strung boss; Damien causes more trouble.
- 15. It-Girl Happened One Night Feb 14, 2011
- Blair is given a challenging assignment and the promise of a possible promotion.
- 16. While You Weren't Sleeping Feb 19, 2011
- Eric turns 18; Serena must choose between Ben and her family.
- 17. Empire of the Son Feb 28, 2011
- Ben's mother visits; Russell risks alienating Raina by resolving to destroy Chuck's family legacy.
- 18. The Kids Stay in the Picture Apr 18, 2011
- William, CeCe and Lily's sister, Carol, visit; Blair realizes who she is destined to be with.
- 19. Petty in Pink Apr 25, 2011
- Serena asks Charlie to help figure out why Blair and Dan are spending so much time together.
- 20. The Princesses and the Frog May 2, 2011
- Serena's actions jeopardize Blair's dreams; Charlie and Vanessa become friendly.
- 21. Shattered Bass May 9, 2011
- Charlie is invited to a Constance Billard fundraiser; Blair is torn between the men in her life.
- 22. The Wrong Goodbye May 16, 2011
- Blair is faced with a difficult decision; Georgina Sparks returns.