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  2. Aug 24, 2022 · NaHCO3 or sodium bicarbonate is a white crystalline solid with molecular mass 84.006g/mol. It is an odorless substance with salty like nature. It is made up of a sodium cation and an anion of bicarbonate. NaHCO3 is used as baking agent in cakes, pyrotechnics, antacids and as fire extinguishers.

    • Overview
    • Cations and anions
    • Naming cations
    • Naming anions
    • Formulas and naming of basic ionic compounds
    • Example 1: Finding the chemical formula from the name
    • Example 2: Finding the name from the chemical formula
    • Try it: Names and formulas of ionic compounds
    • Conclusion

    Learn how to name positive ions (cations), negative ions (anions), and ionic compounds involving main group elements.

    When a neutral atom loses one or more electrons, the total number of electrons decreases while the number of protons in the nucleus remains the same. The result is that the atom becomes a cation—an ion with a net positive charge. For example, the element sodium loses one electron to become a cation:

     

    Similarly, when a neutral atom gains one or more electrons, the result is that the atom becomes an anion—an ion with a net negative charge. For example, the element chlorine gains one electron to become an anion:

     

    Main group elements (the elements in groups 1, 2, and 13-18 of the periodic table) typically form ions of only one charge. The diagram below shows the common charge of ions in different groups.

    Note: Hydrogen is somewhat unusual in that it readily forms both cations and anions. Most elements form only one or the other.

    How do we name main group cations? In general, the cation name is the same as the element name, but with the word "ion" added to the end.

    For example, the alkali metals in group 1 on the periodic table tend to form cations with a 1+‍  charge. The following table shows how we name the ions for the first four elements in this group:

    In speech, we may also refer to a hydrogen cation simply as "H‍ -plus". Similarly, a sodium cation can be called "a sodium ion" or "Na‍ -plus".

    The same rule applies to all other elements that typically form cations of one particular charge. This includes the alkaline earth metals in group 2 and a few other metals you may be familiar with, shown in the table below:

    Why don't we need to include a charge in the names of these ions? For example, why can we say "calcium ion" instead of "calcium-two-plus ion"? Since these main group elements usually form ions of only one charge, which can be predicted from the periodic table, the charge is implied.

    [What about elements that form more than one cation?]

    To name main group anions, we take the root of the element's name and add -ide to the end. The following table shows how this suffix is used to name anions of various elements:

     

    Let's use the oxygen anion as an example. In writing, it is shown as the symbol O2−‍  or written as "oxide". In speech, we'd typically refer to it as an "oxygen ion", "oxide", or "O‍ -two-minus"

    Since we can predict the charge of main group anions by their location on the periodic table, it's usually not necessary to specify their charge in the name. For example, it is implied that an oxide ion has a 2−‍  charge. We don't need to say "oxide-two-minus".

    Now that we've seen the naming conventions for cations and anions, we can discuss how they apply to naming simple ionic compounds (a.k.a. salts). The following guidelines are used for naming ionic compounds:

    •Always name the cation before the anion. The cation will appear before the anion in the chemical formula, too.

    •Any ionic compound will have a net charge of zero. Another way of saying this is that cations and anions must always combine in such a way so that their charges cancel.

    •The number of cations and anions in the formula should be written as the lowest possible integer value. For example, the formula for sodium chloride is NaCl‍ , not Na2Cl2‍  or some other multiple of NaCl‍ , even though the charges would still add up to zero.

    What is the chemical formula of potassium chloride?

    Potassium (K‍ ) is in group 1, so it forms a cation with a 1+‍  charge. Chloride is, by definition, an anion formed from an atom of chlorine (Cl‍ ) . Chlorine is in group 17, so chloride has a 1−‍  charge. The potassium and chloride ions have equal and opposite charges, so they will join in a 1:1 ratio, forming KCl‍ .

    What is the name of the ionic compound Mg3P2‍ ?

    Magnesium (Mg‍ ) is in group 2, so it forms a cation with a 2+‍  charge. Because it is the cation in the compound, we put it first in the compound’s name and refer to it as just magnesium. (Notice we remove the word "ion" since it is now part of a compound).

    Phosphorus (P‍ ) is in group 15, so it forms anions with a 3−‍  charge. Because it is the anion in the compound, we put it second in the compound’s name and refer to the anion by its name, phosphide.

    Therefore, the name for the ionic compound Mg3P2‍  is magnesium phosphide.

    Problem 1

    What is the name of the compound SrF2‍ ?

    Choose 1 answer:

    Choose 1 answer:

    •(Choice A)

    fluoride strontium

    Cations are positively charged ions formed when neutral atoms lose electrons; anions are negatively charged ions formed when neutral atoms gain electrons. It is possible to predict the charges of main group ions by looking at the group numbers on the periodic table.

    To name main group cations, we simply refer to them as the element's name + "ion". To name main group anions, we add the suffix -ide to the end of the element's name.

    Cations and anions combine to form ionic compounds. Ionic compounds are named with the cation first and the anion last. The same convention is used when writing their chemical formulas. Ionic compounds must be electrically neutral. Therefore, the cations and anions combine in such a way that the net charge contributed by the total number of cations exactly cancels the net charge contributed by the total number of anions.

    [Attributions and references]

  3. A cation is a positive ion that forms when a neutral atom loses one or more electrons from its valence shell. An an anion is a negative ion that forms when a neutral atom gains one or more electrons in its valence shell.

  4. A proper ionic formula has a cation and an anion in it; an ionic compound is never formed between two cations only or two anions only. The key to writing proper ionic formulas is simple: the total positive charge must balance the total negative charge.

  5. The way to approach this is to look at the chemical formula and say sodium chloride consists of a sodium cation and a chloride anion. The next step is to analyze the cation and the anion and think about if they react with water or not.

    • 14 min
  6. Mar 3, 2020 · Writing Chemical Formulas. The chemical formula of a compound is always written with the cation first, followed by the anion. For example, Na is the cation and Cl is the anion in NaCl (table salt). The same convention applies to chemical names. The chemical name of table salt is sodium chloride. This works for polyatomic ions, too.

  7. Yes, cations and anions can combine. Because they are polar opposites, they attract each other. They form a binary compound. In this way, for example, sodium ions and chloride anions combine to make table salt. However, ions that are not opposites repel one another, and, therefore, will not combine.

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