2006
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- OverviewSep 20, 2010-May 16, 201124 episodesEpisodes24. Chuck Versus the Cliffhanger May 16, 2011
- Chuck must stop Vivian Volkoff from destroying his and Sarah's wedding.
- 23. Chuck Versus the Last Details May 9, 2011
- Chuck and Sarah work to get Chuck's mother to the wedding alive; Morgan must face Vivian Volkoff.
- 22. Chuck Versus Agent X May 2, 2011
- Chuck's bachelor party turns up uninvited guests; Ellie makes a life-changing discovery.
- 21. Chuck Versus the Wedding Planner Apr 18, 2011
- Chuck and Sarah turn to Sarah's father for help when they are conned out of their wedding money.
- 20. Chuck Versus the Family Volkoff Apr 11, 2011
- Chuck tries to prove Vivian Volkoff's innocence after the CIA orders her assassination.
- 19. Chuck Versus the Muuurder Mar 21, 2011
- Chuck investigates after a murder takes place in Castle; Ellie's new hobby alarms Awesome.
- 18. Chuck Versus the A-Team Mar 14, 2011
- Chuck and Sarah suspect Casey is carrying out private missions; Chuck feels threatened.
- 17. Chuck Versus the First Bank of Evil Feb 28, 2011
- Chuck encourages Vivian to get in touch with her inner villain for a mission.
- 16. Chuck Versus the Masquerade Feb 21, 2011
- The team is sent to England to protect a reclusive heiress; Ellie and Awesome solve a problem.
- 15. Chuck Versus the Cat Squad Feb 14, 2011
- When Chuck reunites Sarah with her former spy team, old grudges and secrets are revealed.
- 14. Chuck Versus the Seduction Impossible Feb 7, 2011
- Casey, Chuck and Sarah are sent to Morocco; Morgan plans to meet Alex's mother.
- 13. Chuck Versus the Push Mix Jan 31, 2011
- While Sarah tries to free Chuck's mother, Morgan and Chuck go after Volkoff.
- 12. Chuck Versus the Gobbler Jan 24, 2011
- Chuck worries about Sarah when she tries to help Mary Bartowski take down Volkoff.
- 11. Chuck Versus the Balcony Jan 17, 2011
- Chuck tries to create a romantic getaway for Sarah while tracking down a nanochip at a vineyard.
- 10. Chuck Versus the Leftovers Nov 29, 2010
- Chuck's mom comes over for "Thanksgiving leftovers" dinner the day after the holiday.
- 9. Chuck Versus Phase Three Nov 22, 2010
- Sarah, Chuck, Morgan and Casey head to the jungles of Southeast Asia.
- 8. Chuck Versus the Fear of Death Nov 15, 2010
- Casey and Morgan try to cover when the "Buy Morons" investigate Greta's identity.
- 7. Chuck Versus the First Fight Nov 1, 2010
- Chuck goes on a rogue mission to avoid confronting Sarah after their first real fight.
- 6. Chuck Versus the Aisle of Terror Oct 25, 2010
- Chuck, Sarah, Casey and Morgan must stop Dr. Stanley from releasing a toxin that induces nightmares.
- 5. Chuck Versus the Couch Lock Oct 18, 2010
- Chuck must decide what he is willing to sacrifice to find his mother.
- 4. Chuck Versus the Coup d'Etat Oct 11, 2010
- Chuck and Sarah join Ellie and Awesome on a trip to Costa Gravas.
- 3. Chuck Versus the Cubic Z Oct 4, 2010
- A prison transfer delivers old foes to the Buy More, canceling Chuck and Sarah's romantic mission.
- 2. Chuck Versus the Suitcase Sep 27, 2010
- Chuck and Sarah go under cover in Milan during Fashion Week to retrieve a high-tech secret weapon.
- 1. Chuck Versus the Anniversary Sep 20, 2010
- Chuck and Morgan search the globe for Chuck's mother; Ellie shares big news.