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- Season 5 overviewDec 15, 2005-Oct 14, 200728 episodesSeason 5 episodes
- An investigation into the two decade hunt for the Green River Killer.
- 2. Finding BTK Dec 22, 2005
- Dennis Rader leaves at least 10 murder victims in his wake.
- 3. Death of a Deacon; A Wife's Mission Jan 14, 2006
- A woman claims she was assaulted by the man that killed her husband.
- 4. Snatched; A Detective's Promise Jan 21, 2006
- Police search for the killer of an 18-year-old hitchhiker and a 6-year-old girl.
- 5. The Sunday Morning Slasher Feb 4, 2006
- Publicity of a man's mandatory release in Texas brings forth a witness to a murder in Michigan.
- 6. Caught on Tape; A Son to Remember Feb 11, 2006
- A cell phone and an ATM card lead to the apprehension of a rapist.
- 7. On the Case: Nacole's Killer Feb 18, 2006
- Detectives work to solve the 1995 rape and murder of a 14-year-old.
- 8. Killer on Campus; The Bow Hunter Apr 2, 2006
- DNA evidence solves a murder; a man confesses to a random killing.
- 9. Something Snapped; A Killer's Dream Apr 7, 2006
- In 1987, a girl is found raped and strangled; in 1983, a young mother is raped and murdered at work.
- 10. Daddy Dearest; A Pastor's Wife May 6, 2006
- A wiretapped conversation cracks a murder case.
- 11. A Killer's Skin; Where's Peggy? Jun 3, 2006
- A police detective suspects a killer preys on older women.
- 12. Innocence Stolen; Danger at the Door Jul 8, 2006
- Girls are sexually assaulted; a 9-year-old girl is found murdered.
- 13. The Interrogation; The Slide Jul 15, 2006
- A young girl is found dead in her home; a woman is raped and murdered.
- 14. The Taunt; Death in Deadwood Jul 29, 2006
- In 1995, two women are raped; in 1982, a young man is found murdered.
- 15. On the Case: A Child Remembers Aug 12, 2006
- Detective Danny Reyes investigates the 1990 murder of a Fort Worth, Texas woman.
- 16. The Black Dahlia Sep 9, 2006
- In 1947, actress Elizabeth Short's corpse is found nude and bisected in an empty lot.
- 17. The Deadly Stroll; Unholy Secret Sep 23, 2006
- A letter opener links a priest to the murder of a nun.
- 18. A Deadly Affair; The Sting Operation Sep 30, 2006
- A banker is beaten to death in his bed; a man with a guilty conscience helps police.
- 19. NCIS; Exhuming the Truth Oct 7, 2006
- A missing sailor's sister works to prove he was killed; rape and murder.
- 20. Cross Country Connection; Eyes at the Window Oct 21, 2006
- The 1988 rape and murder of a California woman; a jailhouse snitch.
- 21. Abandoned Houses; A Son's Memory Oct 28, 2006
- Two young girls are raped and murdered; a 26-year-old mother of three disappears.
- 22. A Knock at the Door; Shattered Nov 18, 2006
- A 25-year-old woman is killed in a hotel room; jewelry-store robbery.
- 23. A Deadly Pattern; A Desperate Housewife Dec 24, 2006
- A woman is found murdered in her mobile home; an Oregon man is shot dead.
- 24. Murder He Wrote; Caught by the Past Dec 31, 2006
- A Detroit cab-company owner is murdered in 1989; in 1986 a woman is found murdered in her bedroom.
- 25. Left for Dead; On the Case Dec 31, 2006
- Fingerprints help track down a sex worker's killer; DNA analysis.
- 26. The Execution of Michael Johnson Jul 26, 2007
- Michael Johnson is scheduled to die by injection, the inmate's family believes is unjust punishment.
- 27. Innocence Files Sep 20, 2007
- College students take on the cases of jailed murderers who claim they are innocent.
- 28. Evidence Kit Oct 14, 2007
- The Women's DNA Initiative helps fund the testing of rape kits.