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- Season 5 overviewJan 14-Nov 18, 196724 episodesSeason 5 episodes1. From Venus With Love Jan 14, 1967
- A blinding light bleaches the corpses of British Venusian Society members; guest Jon Pertwee.
- 2. Fear Merchants Jan 21, 1967
- A ceramics manufacturer's rivals go mad from being subjected to their deepest fears.
- 3. Escape in Time Jan 28, 1967
- An agent dies after stumbling onto a plot to help fugitives escape back into time.
- 4. The See-Through Man Feb 4, 1967
- Steed and Emma look into a formula for making people invisible.
- 5. The Bird Who Knew Too Much Feb 11, 1967
- A parrot named Captain Crusoe appears to relay data on a top-secret missile base.
- 6. Winged Avenger Feb 18, 1967
- A cartoon strip predicts the deaths of people by a winged avenger too accurately.
- 7. Living Dead Feb 25, 1967
- Rumors of a ghost lead Steed and Emma to a country chapel.
- 8. Hidden Tiger Mar 4, 1967
- The only clue to mauling deaths, including those of a farmer and a big-game hunter, is a medallion.
- 9. Correct Way to Kill Mar 11, 1967
- A finishing school for young English gentlemen proves to be a hotbed for murder and espionage.
- 10. Never, Never Say Die Mar 18, 1967
- A walking corpse escapes from a mortuary.
- 11. Epic Apr 1, 1967
- Emma may star in a film about her life, but the ending is her death.
- 12. The Superlative Seven Apr 8, 1967
- Seven fighting experts are unknowingly invited to party to the death.
- 13. A Funny Thing Happened on the Way to the Station Apr 15, 1967
- Steed and Emma race against time to save the prime minister's life.
- 14. Something Nasty in the Nursery Apr 22, 1967
- British peers, privy to defense secrets, hallucinate about their childhoods and their mutual nanny.
- 15. The Joker Apr 29, 1967
- A weekend of bridge in Devonshire ends when a criminal that Emma sent to jail comes seeking revenge.
- 16. Who's Who??? May 6, 1967
- An enemy agent uses his new invention, a machine that switches personalities, on Steed and Emma.
- 17. Return of the Cybernauts Sep 30, 1967
- A dilettante tries to control Steed and Emma through a device in their watches.
- 18. Death's Door Oct 7, 1967
- British conference delegates have strange dreams suggesting impending death.
- 19. The £50,000 Breakfast Oct 14, 1967
- Clues point to an industrialist/financier after a man dies with a cache of diamonds in his stomach.
- 20. Dead Man's Treasure Oct 21, 1967
- Steed and Emma join a car rally to find the missing information that a dead agent has hidden.
- 21. You Have Just Been Murdered Oct 28, 1967
- A gang blackmails millionaires with mock attempts on their lives, then threatens the real thing.
- 22. Positive-Negative Man Nov 4, 1967
- Steed and Emma investigate the death of an electronics expert.
- 23. Murdersville Nov 11, 1967
- A small town is involved in a series of paid murders that are performed by the townsfolk.
- 24. Mission ... Highly Improbable Nov 18, 1967
- A scientist destroys a Treasury official with a shrinking ray, then trains it on Emma and Steed.