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  1. Most important symptoms and effects Notes to Physician. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if symptoms occur.

  2. bpb-us-w2.wpmucdn.com › sites › distSAFETY DATA SHEET

    1-Bromobutane Revision Date 19-January-2018 equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

    • Uses advised against
    • General information
    • Inhalation
    • Suitable extinguishing media
    • Unsuitable extinguishing
    • Specific hazards
    • Hazardous combustion products
    • Protective actions during firefighting
    • Personal precautions
    • Environmental precautions
    • Methods for cleaning up
    • Advice on general occupational hygiene
    • 8.2. Exposure controls
    • Hygiene measures
    • Reactivity
    • Stability
    • Materials to avoid
    • Summary
    • Target organs
    • Specific target organ toxicity - repeated exposure
    • Aspiration hazard
    • Acute aquatic toxicity
    • 14.5. Environmental hazards
    • 14.6. Special precautions for user
    • 15.2. Chemical safety assessment
    • SECTION 16: Other information

    Not suitable for human consumption or veterinary purposes.

    Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medical personnel.

    Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Get medical attention. Place unconscious person on their side in ...

    The product is flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire.

    Do not use water jet as an extinguisher, as this will spread the fire. media

    Containers can burst violently or explode when heated, due to excessive pressure build-up. Flammable liquid and vapour. Vapours may be ignited by a spark, a hot surface or an ember. Vapours may form explosive mixtures with air. Fire-water run-off in sewers may create fire or explosion hazard. Vapours are heavier than air and may spread near ground ...

    Thermal decomposition or combustion products may include the following substances: Harmful gases or vapours. Oxides of carbon. Hydrogen bromide (HBr).

    Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. Ventilate closed spaces before entering them. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the ...

    Wear protective clothing as described in Section 8 of this safety data sheet. No action shall be taken without appropriate training or involving any personal risk. Do not touch or walk into spilled material. Evacuate area. Provide adequate ventilation. No smoking, sparks, flames or other sources of ignition near spillage. Promptly remove any clothi...

    Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment.

    Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely. Eliminate all ignition sources if safe to do so. No smoking, sparks, flames or other sources of ignition near spillage. Do not allow material to enter confined spaces, due to the risk of explosion. Absorb small quan...

    Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimise spills. Keep container tightly sealed when not in use. Avoid the formation of mists. The product is flammable. Ke...

    Protective equipment Appropriate engineering controls Eye/face protection Hand protection Other skin and body protection

    Provide adequate general and local exhaust ventilation. Ensure the ventilation system is regularly maintained and tested. Good general ventilation should be adequate to control worker exposure to airborne contaminants. Observe any occupational exposure limits for the product or ingredients. Unless the assessment indicates a higher degree of protect...

    See the other subsections of this section for further details.

    Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions.

    The following materials may react strongly with the product: Oxidising agents. Exothermic reaction with: Alkali metals. Alkaline earth metals. Powdered metal. Strong oxidising agents. Avoid heat, flames and other sources of ignition. Containers can burst violently or explode when heated, due to excessive pressure build-up. Static electricity and fo...

    Based on available data the classification criteria are not met. Based on available data the classification criteria are not met. Based on available data the classification criteria are not met. Causes skin irritation. Based on available data the classification criteria are not met. Based on available data the classification criteria are not met. B...

    May cause respiratory irritation. Respiratory system, lungs

    Summary May cause damage to organs through prolonged or repeated exposure.

    Summary General information Inhalation Ingestion Skin contact Eye contact Route of exposure

    Summary Acute toxicity - fish Acute toxicity - aquatic invertebrates Acute toxicity - aquatic plants

    Environmentally hazardous substance/marine pollutant

    Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

    No chemical safety assessment has been carried out. Inventories

    This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to ...

  3. 1-Bromobutane Revision Date 30-Sep-2014 P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.

  4. No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.

  5. OSHA Vacated PELs: 1-Bromobutane: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

  6. Product name : 1-Bromobutane Product Number : B59497 Brand : Sigma-Aldrich Company : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # : (314) 776-6555 2. HAZARDS IDENTIFICATION Emergency Overview OSHA Hazards Flammable liquid, Irritant

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