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15 hours ago · Thiourea and its derivatives have become a significant focal point within the organic synthesis field, garnering attention for their diverse biological applications, including antibacterial, antioxidant, anticancer, anti-inflammatory, anti-Alzheimer, antituberculosis and antimalarial properties. My objective is to present a comprehensive and easily understandable analysis of recent ...
15 hours ago · Fig. 1: Synthesis diagram and crystal phase structure and morphology analysis. a Schematic diagram for the synthesis of Ni/BWO, XRD patterns, 2θ from 25° to 35° ( b ), FT-IR spectra ( c ), and ...
2 days ago · The identity of 42 was confirmed by the independent synthesis of an authentic sample, as shown in Scheme 10. The first step involved the phase-transfer catalyzed addition of dibromocarbene to DHN, giving dibromocyclopropane 43, a known compound. Addition of MeLi to 43 and subsequent reaction with iodomethane gave alkyl halide 44.
4 days ago · Reverse water-gas shift reaction. The reverse water-gas shift reaction (RWGS) is a pathway for converting hazardous CO 2 to CO (a constituent of syngas), which itself can be further used in methanol synthesis and other procedures. To accelerate this reaction, MXene-based substances are valuable and have shown promise.
3 days ago · A new strategy to obtain β,γ-unsaturated ketones via the cross-coupling of 1,3-butadiene, alkyl bromides, and arylboronic acids under 1 bar of CO with nickel as the catalyst has been developed. This newly developed four-component carbonylation procedure features advantages including using a cheap catalytic system, high step economy, mild reaction conditions, and excellent 1,4 ...
3 days ago · Organic Synthesis Textbook with a reation-based focus, incorporating molecular modeling content, problems, and visualizations, and includes reaction examples and homework problems drawn from the latest in the current literature. The first chapter reviews basic retrosynthesis, conformations and stereochemistry.
1 day ago · For example, the atomic composition of complex-3 was recorded by EDX. Figure 1 a shows the energy signals consistent with the chemical content of complex-3; it displays the presence of a signal for Pd, Cl, O, N, and C only; no other signals appeared, which reflected the high degree of purity and confirmed the absence of any side products or ...
