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Oct 28, 2020 · A relatively small number of guest molecules with a shorter induction time for pure guest hydrate nucleation can promote the formation of initial nuclei of a mixed hydrate. Detailed cage analysis shows that small guests such as CH 4 can induce the formation of more standard cages for mixture systems with either C 2 H 6 or C 3 H 8 systems ...
Jan 19, 2021 · We demonstrate that the CH 4 –CO 2 guest composition impacts the guest–host interactions in hydrates during static temperature measurements at 10 K, implying that these interactions are ...
- Bernadette R. Cladek, S. Michelle Everett, Marshall T. McDonnell, Matthew G. Tucker, David J. Keffer...
- 2021
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Aug 28, 2015 · This article has highlighted the state-of-the-art potential energy applications of crystalline guest-host compounds, the inorganic and water (hydrates) clathrates. The guest-host interactions of these compounds play a significant role in the structure, stability, and properties of these materials.
- Lakshmi Krishna, Carolyn A. Koh
- 2015
Aug 3, 2021 · Though a simple host–guest system can be obtained just by the simple mixing of macrocyclic hosts and guest molecules, the design of complex supramolecular assemblies with varied morphologies and functions requires the synergetic integration of various factors like the strength of the host–guest binding, nature of the macrocyclic hosts and ...
Aug 12, 2021 · The study thus gave a novel example of a host–guest mixture that is able to carry out composition-driven structural modulation and guest-induced nanotemplates. The finding broadens the horizon of host–guest chemistry and may inspire more nanoinnovation.
- Jou Tsen Ou, Tsung Kai Yang, Heng Yi Lin, Hong Yu Hsu, Tzu Jung Chen, Yi Sheng Ou, Jia Chen, Cheng Y...
- 2021
Host–guest complexes can be seen to arise from the coordination of a cationic, anionic, or neutral guest entity within a discrete host molecule or supramolecular host assembly, using noncovalent interactions, such as H-bonds, ionic bonds, van der Waals forces, and hydrophobic interactions.
Oct 29, 2020 · X-ray single crystal analysis revealed a 1: 1 host–guest inclusion complex of the composition [dMV @ CPA5]·5.27(H 2 O) in the P 2 1 / c space group of the monoclinic system. The asymmetric unit comprises one CPA5 molecule, one paraquat cation (modelled as disordered over two positions) included into the host cavity, and water molecules.
