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- Season 3 overviewSep 14, 2009-May 17, 201022 episodesSeason 3 episodes1. Reversals of Fortune Sep 14, 2009
- Serena returns from Europe with secrets and a complicated relationship.
- 2. The Freshman Sep 21, 2009
- Georgina is determined to make Blair a social outcast; Serena tries to get even with Chuck.
- 3. The Lost Boy Sep 28, 2009
- Serena thinks Carter is up to his old habits; Georgina becomes interested in Dan.
- 4. Dan De Fleurette Oct 5, 2009
- A movie star named Olivia Burke is assigned as Vanessa's roommate at NYU.
- 5. Rufus Getting Married Oct 12, 2009
- Georgina pulls Vanessa and Dan into one of her schemes; Blair grows suspicious of Bree.
- 6. Enough About Eve Oct 19, 2009
- Vanessa vies with Blair for the honor of delivering the freshman toast.
- 7. How to Succeed in Bassness Oct 26, 2009
- Jenny must choose between her role as Queen Bee and her friendship with Eric.
- 8. The Grandfather: Part II Nov 2, 2009
- Blair makes a new friend and takes her to a party in hopes of making Serena jealous.
- 9. They Shoot Humphreys, Don't They? Nov 9, 2009
- Chuck and Nate try to help Serena and Blair repair their friendship.
- 10. The Last Days of Disco Stick! Nov 16, 2009
- Blair tries to impress students at NYU with a private Lady Gaga concert.
- 11. The Treasure of Serena Madre Nov 30, 2009
- Blair suspects her mother of keeping a big secret from her; Vanessa shows up on Dan's doorstep.
- 12. The Debarted Dec 7, 2009
- Vanessa and Dan try to navigate their newly complicated friendship.
- 13. The Hurt Locket Mar 8, 2010
- Serena and Nate explore the boundaries of their friendship; Rufus tries to avoid Lily.
- 14. The Lady Vanished Mar 15, 2010
- Lily and Rufus become suspicious of Jenny's relationship with Damien.
- 15. The Sixteen Year Old Virgin Mar 22, 2010
- Damien pressures Jenny; Chuck makes a difficult decision about his hotel.
- 16. The Empire Strikes Jack Mar 29, 2010
- Chuck is again at odds with Jack Bass; Eleanor puts Blair in charge of the fashion show.
- 17. Inglorious Bassterds Apr 5, 2010
- Blair and Chuck face a difficult decision; Serena plans a surprise party for Nate.
- 18. The Unblairable Lightness of Being Apr 12, 2010
- Dorota asks Chuck and Blair to be a part of her wedding; Serena secretly meets with Carter.
- 19. Dr. Estrangeloved Apr 26, 2010
- Nate and Serena continue to have relationship issues; Dan gets upsetting news.
- 20. It's a Dad, Dad, Dad World May 3, 2010
- Dan discovers that Vanessa has been keeping another secret from him.
- 21. Ex-Husbands and Wives May 10, 2010
- Chuck makes one last grand gesture in hopes of winning Blair back.
- 22. Last Tango, Then Paris May 17, 2010
- Blair must decide if she wants to have a future with Chuck; Georgina returns with an agenda.