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- Season 1 overviewSep 30, 2001-May 12, 200222 episodesSeason 1 episodes1. Truth Be Told Sep 30, 2001
- A graduate student working for the CIA reveals her secret, endangering lives.
- 2. So It Begins Oct 7, 2001
- Sydney travels to Moscow to recover stolen files, then to Cairo to face a deadly foe.
- 3. Parity Oct 14, 2001
- Sydney encounters her nemesis while retrieving a 500-year-old sketch in Madrid.
- 4. A Broken Heart Oct 21, 2001
- Francie confronts her boyfriend; Sydney reaches out to her estranged father.
- 5. Doppelganger Oct 28, 2001
- The questionable identity of a biotech engineer stokes Sloane's suspicions about Sydney.
- 6. Reckoning Nov 18, 2001
- Sydney goes under cover in a mental hospital to get information from an assassin.
- 7. Color-Blind Nov 25, 2001
- Sydney helps Shepard escape from the asylum.
- 8. Time Will Tell Dec 2, 2001
- Sloane's search for a mole forces Sydney to take a polygraph test.
- 9. Mea Culpa Dec 9, 2001
- Sloane's superior tells him that Sydney is the mole; Dixon is shot while on a mission.
- 10. Spirit Dec 16, 2001
- Vaughn gives Sydney a Christmas gift; Sydney is suspected of being the SD-6 mole.
- 11. The Confession Jan 6, 2002
- Vaughn uncovers evidence suggesting Jack may be responsible for the deaths of CIA agents.
- 12. The Box Jan 20, 2002
- An ex-agent (Quentin Tarantino) leads armed intruders in a takeover of SD-6.
- 13. The Box Feb 10, 2002
- Vaughn helps Sydney and Jack save SD-6 headquarters from McKenas Cole.
- 14. The Coup Feb 24, 2002
- Sydney and Dixon seek an agent in Las Vegas who has ties to the group that attacked SD-6.
- 15. Page 47 Mar 3, 2002
- Vaughn asks Sydney to gain access to a book in Sloane's home.
- 16. The Prophecy Mar 10, 2002
- The DSR tests Sydney to discover her link to a 500-year-old Rambaldi prophecy.
- 17. Q & A Mar 17, 2002
- The FBI questions Sydney about her connection to a mysterious Rambaldi prophecy.
- 18. Masquerade Apr 7, 2002
- Sydney encounters an ex-lover who broke her heart five years earlier.
- 19. Snowman Apr 14, 2002
- Passion ignites between Sydney and Noah, while Sloane questions Noah's allegiance.
- 20. The Solution Apr 21, 2002
- Sydney and Vaughn arrange the sale of a Rambaldi artifact in order to catch Khasinau.
- 21. Rendezvous May 5, 2002
- Will's world starts to crumble as he probes deeper into SD-6 and the leak.
- 22. Almost Thirty Years May 12, 2002
- Sydney and Vaughn must destroy a device in order to save Will's life.
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