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Yes you can, but you'll have to have 2 separate accounts. One with Game Pass Ultimate and one without. Put Game Pass Ultimate on your account. Have your account on his Xbox. Make his Xbox your Home Xbox. All accounts on your Home Xbox have access to Game Pass Ultimate. He should sign in with his account.
Sooooo same player from 2 devices is not a possible thing. Yes, you can with no problem. You have to iniciate the main gamepass account in your microsoft account, your brother account, and in the xbox app on pc, start your main xbox account. Your brother can play in Xbox and you in PC with no problem.
