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Mar 3, 2010 · Chromates have also been demonstrated to be effective oxidants to synthesize nitrosoarenes from aryl amines (Scheme 78).For example, Grundon and co-workers reported that exposure of 520 to chromic acid—generated in situ from mixing potassium dichromate with sulfuric acid—produced nitrosoarene 521 in 88%. 382 The synthesis of nitrosoarenes from N-hydroxylaryl amines is not limited to using ...
Feb 6, 2010 · IUPAC Standard InChI: InChI=1S/C12H17N/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1,3-4,7-8,12-13H,2,5-6,9-10H2 Copy IUPAC Standard InChIKey: TXTHKGMZDDTZFD-UHFFFAOYSA-N ...
N-Ethyl-1-phenylcyclohexylamine (3) (Procedure B).--A solu- tion of 76 g (0.5 mole) of 25 in 200 ml of Et90 was added to PhLi [prepared from 236 g (1.5 moles) of PhBr and 25 g of I,i ribbon in 800 ml of Et201 at such a rate that a gentle reHux w-as maintained. The mixture was heated and stirred 30 min, then filtered quickly,
T1 - The synthesis of phencyclidine and other 1-arylcyclohexylamines. AU - Maddox, V.H. AU - Godefroi, E.F. AU - Parcell, R.F. PY - 1965. Y1 - 1965. N2 - Various 1-arylcyclohexylamines were synthesized for evaluation as central nervous system depressants.
Sep 1, 2021 · N -cyclohexylidenecyclohexanamine and N -phenylcyclohexylamine. The latter one is the dominant product of dicyclohexylamine dehydrogenation. ... (ATA)-catalyzed synthesis of chiral amines, the ...
An attractive procedure from the standpoint of clandestine synthesis would be the reductive alkylation of PCA with acetone and aluminum amalgam to give the potent analog N-isopropyl phenylcyclohexylamine. The first method using PCA as an intermediate is Scheme IV. This route has received little attention among clandestine chemists, but has ...
Phencyclidine, or 1- (1-phenylcyclohexyl) piperidine, is synthesized from piperidine and cyclohexanone. It is a highly lipid-soluble solid that is soluble in both water and alcohol. It is a weak base with a pKa between 8.6 and 9.4. The dose of PCP varies depending on the amount of active drug and the route.
