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- Season 5 overviewSep 26, 2011-May 14, 201224 episodesSeason 5 episodes1. Yes, Then Zero Sep 26, 2011
- Serena makes a mistake at work; Chuck, Nate and Serena attend a party in the Hollywood Hills.
- 2. Beauty and the Feast Oct 3, 2011
- Serena forces Charlie to make a decision; Blair's future sister-in-law visits.
- 3. The Jewel of Denial Oct 10, 2011
- Chuck tries to help Dan accept his fate; Serena returns to the Upper East Side.
- 4. Memoirs of an Invisible Dan Oct 17, 2011
- Dan brings Serena, Blair, Nate, Chuck, Rufus and Lily together to talk about his book.
- 5. The Fasting and the Furious Oct 24, 2011
- While celebrating Yom Kippur, Blair and Louis wind up in a power struggle with his family.
- 6. I Am Number Nine Nov 7, 2011
- Blair's former minions and Charlie compete for a spot in the royal bridal party.
- 7. The Big Sleep No More Nov 14, 2011
- Diana targets Serena; Dan's book tour leads to misunderstandings with friends and family.
- 8. All the Pretty Sources Nov 21, 2011
- Serena hosts a wedding shower for Blair; Nate feels conflicted after making a discovery.
- 9. Rhodes to Perdition Nov 28, 2011
- Lily, Serena and Charlie eagerly anticipate a Studio 54 party thrown in honor of CeCe.
- 10. Riding in Town Cars With Boys Dec 5, 2011
- Lily throws a party for Charlie; Charlie's ex interferes with her future.
- 11. The End of the Affair? Jan 16, 2012
- Blair reveals what happened in the aftermath of her car accident with Chuck.
- 12. Father and the Bride Jan 23, 2012
- Schemers plan to make Blair's bachelorette party memorable; Dan and Serena pretend to date.
- 13. G.G. Jan 30, 2012
- Chuck struggles to face reality as Blair prepares to walk down the aisle with Prince Louis.
- 14. The Backup Dan Feb 6, 2012
- Blair struggles with a decision that could hurt people she loves; Georgina pursues a scandal.
- 15. Crazy, Cupid, Love Feb 13, 2012
- Blair plays cupid for someone important to her; Georgina crashes Nate's Valentine's Day party.
- 16. Cross Rhodes Feb 20, 2012
- Blair tries to save her friendship with Serena; Ivy collides with the van der Woodsens.
- 17. The Princess Dowry Feb 27, 2012
- Georgina and Chuck embark on a scheme that results in a surprising outcome.
- 18. Con Heir Apr 2, 2012
- Dan and Blair encounter unexpected obstacles as they try to consummate their new relationship.
- 19. It Girl, Interrupted Apr 9, 2012
- Serena decides to make Lola the new "It Girl"; Chuck asks Blair for advice.
- 20. Salon of the Dead Apr 16, 2012
- Dan and Blair plan an event to celebrate their official coming-out as a couple.
- 21. Despicable B Apr 23, 2012
- Blair devises a plan to make sure she retains her status on the Upper East Side.
- 22. Raiders of the Lost Art Apr 30, 2012
- Nate, Chuck, Serena, Blair and Lola investigate a secret involving Jack and Diana.
- 23. The Fugitives May 7, 2012
- Blair asks Serena to pose as her at an important meeting; Lola and Ivy help Chuck.
- 24. The Return of the Ring May 14, 2012
- Lily makes a decision about her marriage; Blair makes a choice between Dan and Chuck.